In Situ Synthesis of Graphene Oxide-Sealed LDHs Coatings: A Novel Approach to Enhancing Corrosion Resistance and Tribological Performance on Magnesium Alloys

Abstract

This study introduces an innovative approach to enhancing the corrosion resistance and tribological performance of magnesium alloys by in situ growing zinc-aluminum layered double hydroxide (ZnAl-LDHs) with graphene oxide (GO) sealing. Traditional LDHs coatings exhibit limitations in corrosion protection due to their porous structure. This paper advances the LDHs coating technology by integrating GO, forming a composite LDHs/GO coating on magnesium alloys. The novel incorporation of GO provides a unique two-layered defense system against corrosion: the GO layer serves as a high-resistance barrier to corrosive agents, while the LDHs layer absorbs NO3− ions, offering a secondary protection. The coating’s properties were meticulously characterized using techniques such as scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Fourier-transform infrared (FTIR) Raman spectroscopy, electrochemical assays, and friction-wear tests. Experimental findings reveal that the synergistic action between LDHs and GO results in significant improvements in corrosion resistance and friction reduction. Specifically, GO’s adherence to the LDHs coating’s pores and its ability to transfer into the friction layer during wear significantly enhances the coating’s integrity and stability. The successful in situ synthesis of LDHs /GO coatings opens new horizons for composite coatings, with potential implications across various industrial applications.