Corrosion Behaviors of Tetrasodium Iminodisuccinate (IDS) as an Environmentally Friendly Inhibitor: Experimental and Theoretical Studies

Author:

Fu Shaopeng1,Yang Xingyao1,Peng Yichun2,Wang Qi1,Sun Qinghao1,Zhang Junwei2,Wang Xinping2,Liang Zezhou3,Li Jianfeng1ORCID

Affiliation:

1. School of Materials Science and Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

2. School of Civil Engineering, Lanzhou Institute of Technology, Lanzhou 730050, China

3. School of Electronics Science & Engineering, Faculty of Electronic and Information Engineering, Xi’an Jiaotong University, Xi’an 710049, China

Abstract

An environmentally friendly chelating agent, tetrasodium iminodisuccinate (IDS), was investigated as an inhibitor in the simulated concrete pore solution on Q235 carbon steel by using Tafel polarization (TF), electrochemical impedance spectroscopy (EIS) and surface morphology tests. The EIS and TF results indicate that the IDS is a mixed type of inhibitor and exhibits excellent protection efficiency (97.54%) at 200 mg/L. Furthermore, based on the Langmuir adsorption isotherm, IDS protects carbon steel through physical and chemical adsorption. Besides, density functional theory (DFT) and molecular dynamics (MD) simulations are applied to explore the inhibition mechanism to support the experimental data, indicating that IDS can be used as a new green corrosion inhibitor.

Funder

Innovation and Entrepreneurship Training Program

Publisher

MDPI AG

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces

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