The Development of a Novel Thin Film Test Method to Evaluate the Rain Erosion Resistance of Polyaspartate-Based Leading Edge Protection Coatings

Abstract

The relationship between the bulk thermomechanical properties and rain erosion resistance of development polyaspartate-based coatings as candidate leading edge protection (LEP) materials for wind turbine blades is investigated by the combined application of dynamic mechanical analysis (DMA) and rain erosion testing (RET) within a novel test method (DMA+RET). This method introduces the use of DMA+RET to both monitor the change in thermomechanical properties with respect to raindrop impact and subsequently rationalise differences in rain erosion resistance between coating formulations of comparable composition. The application of this combined process has demonstrated the importance of relatively high viscoelastic moduli at increased strain rates and creep recovery after RET as key material properties to be considered for LEP material development, whereas previous research presented in the scientific literature has primarily focussed on the use of routine characterisation procedures by tensile testing or stand-alone DMA to evaluate coating formulations prior to rain erosion testing. This journal article therefore presents a novel method to evaluate key material properties relevant to rain erosion resistance before and after subjection to raindrop impact using standard ASTM G73 RET equipment. The test method is demonstrated on a novel polyaspartate-based coating, PA-U, that exhibits notable rain erosion resistance in comparison to commercial LEP products. PA-U exhibited negligible mass loss after 30 h of rain erosion testing and favourable thermomechanical properties (E″ = 35 MPa at critical strain; equilibrium recoverable compliance of 0.05 MPa−1) in comparison to alternative formulations.