Synthesis of CoFe2O4 through Wet Ferritization Method Using an Aqueous Extract of Eucalyptus Leaves

Author:

Gingasu Dana1ORCID,Culita Daniela C.1ORCID,Calderon Moreno Jose Maria1,Marinescu Gabriela1,Bartha Cristina2ORCID,Oprea Ovidiu3ORCID,Preda Silviu1ORCID,Chifiriuc Mariana Carmen456ORCID,Popa Marcela5ORCID

Affiliation:

1. Ilie Murgulescu Institute of Physical Chemistry, Romanian Academy, 202 Splaiul Independentei, 060021 Bucharest, Romania

2. National Institute of Materials Physics, 405A Atomistilor Street, P.O. Box Mg-7, 077125 Magurele, Romania

3. Faculty of Chemical Engineering and Biotechnologies, University Politehnica of Bucharest, 1-7 Polizu Street, 011061 Bucharest, Romania

4. Microbiology Department, Faculty of Biology, University of Bucharest, 91-95 Splaiul Independentei, 050095 Bucharest, Romania

5. Research Institute of the University of Bucharest—ICUB, University of Bucharest, 91-95 Splaiul Independentei, 050095 Bucharest, Romania

6. Romanian Academy, 125 Calea Victoriei, 010071 Bucharest, Romania

Abstract

This study explored a new green approach of the wet ferritization method to obtain magnetic cobalt ferrite (CoFe2O4) by using eucalyptus leaves aqueous extract as a reducing/chelating/capping agent. The spinel single cubic phases of prepared samples were proved by powder X-ray diffraction (XRD), Fourier-Transform Infrared (FTIR) and Raman spectroscopy. The average crystallite size is in the range between 3 and 20 nm. The presence of the functional groups coating the obtained material is confirmed from FTIR and thermal analysis. The scanning electron microscopy (SEM) analysis showed a morphology consisting of nanoparticle aggregates. Raman spectroscopy detects the characteristic bands of spinel-type CoFe2O4. Magnetic investigations reveal the formation of ferromagnetic compounds with cubic magnetic anisotropy and a blocking temperature around 140 K, specific for this type of material. The biosynthesized CoFe2O4 could be an attractive candidate for biomedical applications, exhibiting promising antimicrobial and antibiofilm activity, particularly against Gram-negative bacteria and fungal strains.

Funder

Romanian Ministry of Research and Innovation (MCI), UEFISCDI

Publisher

MDPI AG

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces

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