Liquid Phase Deposition of TiO2 on a Multifunctional Template of Grafted Gallic Acid and Hexamethylenediamine (GAHD) with Enhanced Electrochemical Properties

Author:

Lei Huili123,Zhang Xuan13,Chen Si13ORCID,Li Chengbo134,Wan Guojiang13ORCID

Affiliation:

1. Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Chengdu 610031, China

2. College of Chemistry & Pharmacy, Northwest A&F University, Yangling, Xianyang 712100, China

3. School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China

4. Guangxi Key Laboratory of Advanced Structural Materials and Carbon Neutralization, Guangxi Minzu University, Nanning 530006, China

Abstract

Liquid phase deposition is a cost-effective and energy-efficient method for obtaining TiO2 films at low temperatures. This work demonstrates the use of a multifunctional template consisting of grafted gallic acid (GA) and hexamethylenediamine (HD) on a Ti substrate to regulate the deposition of TiO2 films. X-ray diffraction characterization shows that films deposited with the template have a more obvious anatase phase compared to direct deposition at 25 °C. The intensity of photoluminescence spectra also shows significant differences at 373.7 nm and 663.3 nm. Furthermore, electrochemical measurements indicate that TiO2 films adjusted by the template have excellent electrochemical conversion properties. This proposed method provides a new simple route for fabricating TiO2 films that are adjusted by GAHD templates, which may have good applications in the fields of semiconductor materials and biological materials.

Funder

National Key Research and Development Program of China

Sichuan Province Science and Technology Support Program

Science and Technology of Guangxi for Base and Talent Project

Publisher

MDPI AG

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces

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