Hierarchical Porous Activated Carbon Derived from Pleurotus Eryngii and the Influence of Pore Structural Parameters on Capacitance Performance

Abstract

Hierarchical porous activated carbon derived from pleurotus eryngii was prepared by a one-step activation method. It was found that the specific surface area of the obtained sample increased with the increase in activation temperature (700–900 °C). The sample activated at 900 °C has a specific surface area of 2002.2 m2 g−1 and the highest specific capacitance (319 F g−1), which is mainly attributed to the high utilization rate of specific surface area brought by the hierarchical porous structure. The assembled PEK-900//PEK-900 capacitor measured a specific capacity of 258 F g−1 at a current density of 0.5 A g−1. After 10,000 cycles of charging and discharging, the specific capacitance increased by 10%. Based on the correlation analysis of experimental data between the specific capacitance and pore structural parameters, Lasso dimensionality reduction and binary linear regression were used to reveal the relationship between the two. The residual sum of squares obtained by this method decreased by 38.4% compared to the univariate linear regression, providing a simple and reliable theoretical method for predicting the capacitance performance of biomass carbon materials.