Sequence and Characteristics of Atomic Ordering in Ni2Mn1−xCuxGa Ferromagnetic Shape Memory Alloys

Abstract

Post-quench atomic reordering processes undergone by Ni2Mn1−xCuxGa alloys have been characterized in detail. The obtained results corroborate the hypothesis that proposes an atomic ordering process additional to the B2↔L21 one, consisting of the relocation in the Mn sublattice of Cu atoms misplaced by quench in the Ni sublattice. In addition, the results suggest that the ordering of the Cu atoms and the L21 ordering can occur in different sequences depending on the starting state of order. The analysis of the saturation magnetization validates the occurrence of two types of atomic movements; the values corresponding to different post-quench stages have been compared with those calculated for different atomic configurations, supporting the relocation mechanism of Cu atoms as the most plausible mechanism. The effect of the quenching temperature on the reordering processes has been also studied, and an assessment of the degree of quenched disorder is provided, suggesting the existence of an order–disorder transition associated with Cu atoms ordering. Finally, the effect of the Cu amount has been analyzed, confirming that a greater amount of Cu intensifies the process associated to ordering of Cu atoms, which takes place even in martensite.