Facile and Low-Cost Fabrication of SiO2-Covered Au Nanoislands for Combined Plasmonic Enhanced Fluorescence Microscopy and SERS

Author:

Vidal Alejandro1,Molina-Prados Sergio2ORCID,Cros Ana3,Garro Núria3ORCID,Pérez-Martínez Manuel4ORCID,Álvaro Raquel1,Mata Gadea4,Megías Diego4,Postigo Pablo A.15ORCID

Affiliation:

1. Instituto de Micro y Nanotecnología de Madrid (IMN-CSIC), Tres Cantos, 28760 Madrid, Spain

2. GROC-UJI, Institut de Noves Tecnologíes de la Imatge (INIT), Universitat Jamue I, 28760 Tres Cantos, Spain

3. Institut de Ciència dels Materials (ICMUV), Universitat de València, 46071 Valencia, Spain

4. Confocal Microscopy Unit, Centro Nacional de Investigaciones Oncológicas (CNIO-ISCIII), 28029 Madrid, Spain

5. The Institute of Optics, University of Rochester, Rochester, New York, NY 14627, USA

Abstract

An easy and low-cost way to fabricate monometallic Au nanoislands for plasmonic enhanced spectroscopy is presented. The method is based on direct thermal evaporation of Au on glass substrates to form nanoislands, with thicknesses between 2 and 15 nm, which are subsequently covered by a thin layer of silicon dioxide. We have used HR-SEM and AFM to characterize the nanoislands, and their optical transmission reveals strong plasmon resonances in the visible. The plasmonic performance of the fabricated substrates has been tested in fluorescence and Raman scattering measurements of two probe materials. Enhancement factors up to 1.8 and 9×104 are reported for confocal fluorescence and Raman microscopies, respectively, which are comparable to others obtained by more elaborated fabrication procedures.

Funder

Spanish Ministerio de Ciencia, Innovación y Universidades

Comunidad de Madrid

MINECO

EU

Spanish MICINN/AEI

Generalitat Valenciana

MCIN with funding from European Union NextGenerationEU

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

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