Affiliation:
1. School of Civil Engineering, Northeast Forestry University, Harbin 150040, China
2. College of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, China
Abstract
In order to explore the diffusion and regeneration of bio-oil in aged bitumen, waste cooking oil (WCO), waste wood oil (WWO) and straw liquefied residue oil (SLRO) were selected in this paper. According to the surface wetting theory, the contact angle is obtained by combining laboratory experiments with molecular dynamics (MD) simulation, and the wetting parameters are calculated to evaluate the wetting behavior of bio-oil. The experimental phenomena of the wetting process and the main factors driving wetting are further analyzed. A permeation experiment is designed to obtain the permeation fusion layer (PFL). If the crossover modulus of PFLs changes compared with that of the aged bitumen, it is determined that the bio-oil penetrates the corresponding fusion layer. The results show that the motion of bio-oil included spreading and shrinking processes, and a precursor film played a pivotal role in the transportation of nanodroplets. Higher surface tension, lower viscosity and cohesion can effectively promote the wettability of bio-oil. A higher temperature and a longer permeation time are conducive to the permeation of bio-oil in aged bitumen. WCO with the strongest wettability has the weakest permeability, while WWO has superior permeability and can activate the macromolecules’ surface activity, but its wettability is relatively weak. It is necessary to further modify WCO and WWO to be suitable rejuvenators.
Funder
Department of Transportation of Heilongjiang Province
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Computer Science Applications,Spectroscopy,Molecular Biology,General Medicine,Catalysis
Cited by
1 articles.
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