Influence of Temperature in Degradation of Organic Pollution Using Corona Discharge Plasma

Abstract

Dye solution temperature influences the elimination efficiency of water-soluble and anionic acid dye. Acid Blue 25 dye, using a gas–liquid electrical discharge system, was successfully investigated. The results showed an increase in the percentage of dye decolorization from 91.16% to 96.12% when the dye solution temperature was increased from 278 K to 308 K. However, the initial dye decolorization percentage was decreased with the further increase in dye solution temperature from 318 K to 358 K. The 2D simulation model was introduced to consider the influence of temperature and the electric field generated by corona discharge plasma in air and water. Results also showed a great match between the experimental and the simulation results. The reaction rates of dye degradation were analyzed using the Arrhenius equation. Furthermore, pseudo-zero-, pseudo-first-, and pseudo-second-order models were used to determine the reaction kinetics. The best fit for the experimental data would follow the pseudo-first-order model. Finally, electrical energy per order, energy yield, and experimental degradation data were calculated to investigate the cost analysis.