Study on Preparation and Performance of CO2 Foamed Concrete for Heat Insulation and Carbon Storage

Abstract

Environmental problems caused by large amounts of CO2 generated by coal–electricity integration bases have raised concerns. To solve these problems, this study develops a CO2 foam concrete (CFC) material with both heat insulation and carbon fixation characteristics to realize CO2 in situ storage and utilization. In this study, a Portland-cement-based CO2 foam concrete (PC-CFC) with good thermal insulation performance and carbon fixation ability is prepared using carbonation pretreatment cement and a physical foaming method. The effects of CO2 on the compressive strength, thermal insulation, and carbon fixation properties of PC-CFC are studied. The internal relationship between the compressive strength, thermal insulation, and carbon fixation performance of PC-CFC is analyzed, and the feasibility of PC-CFC as a filling material to realize the in situ mineralization and storage of CO2 in the coal–electricity integration base is discussed. The experimental results show that the compressive strength of PC-CFC is significantly improved by CO2 curing. However, CO2 in the PC-CFC pores may weaken the strength of the pore structure, and the compressive strength decreases by 3.62% for each 1% increase in PC-CFC porosity. Using CO2 as a foaming gas and the physical foaming method to prepare CFC can achieve improved thermal insulation performance. The thermal conductivity of PC-CFC is 0.0512–0.0905 W/(m·K). In addition, the compressive strength of PC-CFC increases by 19.08% when the thermal conductivity of PC-CFC increases by 1%. On the premise of meeting the thermal insulation requirements, PC-CFC can achieve improved compressive strength. The carbon sequestration rate of the PC-CFC skeleton is 6.1–8.57%, and the carbon storage capacity of PC-CFC pores is 1.36–2.60 kg/ton, which has obvious carbon sequestration potential; however, the preparation process and parameters of PC-CFC still require further improvement. The research results show that PC-CFC has great potential for engineering applications and is of great significance for realizing carbon reduction at the coal–electricity integration base.