Green Synthesis and Pinning Behavior of Fe-Doped CuO/Cu2O/Cu4O3 Nanocomposites

Abstract

Egg white-induced auto combustion has been used to synthesize undoped and Fe-doped CuO/Cu2O/Cu4O3 nanocomposites in a soft, secure, and one-pot procedure. X-ray powder diffraction (XRD) and Fourier transform infrared (FTIR) investigations have been used to identify functional groups and the structural properties of crystalline phases present in the as-synthesized composites. Scanning Electron Microscopy/Energy Dispersive Spectrometry (SEM/EDS) elemental mapping analyses and Transmission Electron Microscopy (TEM) techniques were used to explore the morphological and compositional properties of these composites. N2-adsorption/desorption isotherm models have been used to examine the surface variables of the as-prepared systems. Based on the Vibrating Sample Magnetometer (VSM) technique, the magnetic properties of various copper-based nanocomposites were detected due to being Fe-doped. XRD results showed that the undoped system was composed of CuO as a major phase with Cu2O and Cu4O3 as second phases that gradually disappeared by increasing the dopant content. The crystalline phase’s crystallographic properties were determined. The average particle size was reduced when the synthesized systems were doped with Fe. The construction of porous and polycrystalline nanocomposites involving Cu, Fe, O, and C components was confirmed by SEM/EDS and TEM measurements. In terms of the increase in magnetization of the as-manufactured nanocomposites due to Fe-doping, oxygen vacancies at the surface/or interfacial of nanoparticles, while also domain wall pinning mechanisms, were investigated. Finally, employing the investigated production process, Fe doping of CuO/Cu2O/Cu4O3 nanocomposite resulted in the development of a single phase (CuO) exhibiting “pinned” type magnetization. This is the first publication to show that CuO/Cu2O/Cu4O3.