Thermodynamics Analysis and Pilot Study of Reusing Medium and High Alloy Steel Scrap Using Induction Melting and Electroslag Remelting Process

Abstract

The annual cumulative quantity of high and medium alloy steel scrap has exceeded 10 million tons. Using the traditional smelting process involving electric arc refining in a smelting furnace for these scraps causes high percentages of alloy losses, which decreases the value of the alloy steel scrap and poses environmental threats. Existing studies have rarely focused on separate smelting of the scrap and oxidation behaviors of the alloying elements. Therefore, this study proposes an induction melting and electroslag remelting scheme to process the scrap. Based on this scheme, the effects of the temperature, oxygen content, and element contents on the recovery percentages of the alloying elements were investigated using pilot experiment and thermodynamic analysis. The experimental results showed that the alloying elements (tungsten, chromium, nickel, molybdenum, and vanadium) exhibited recovery percentages of 97.36%, 94.62%, 97.63%, 95.09%, and 89.49%, respectively; furthermore, the impurity content did not increase during smelting. The thermodynamic analysis indicated that an increase in carbon content improved the oxidation resistance of the alloying elements except for nickel, whereas the increases in the contents of oxygen and alloying elements increase their oxidation. Steam partial pressure and air suction dramatically increase the concentrations of nitrogen, hydrogen and oxygen. This scheme is an alternative for smelting medium and high alloy steel scrap, and the thermodynamic analysis provides a theoretical understanding of the oxidation behaviors of the alloying elements in the steel scrap and the control of impurity.