Nickel Ions Activated PbO–GeO2 Glasses for the Application of Electrolytes and Photonic Devices

Abstract

In this study, PbO–GeO2 glasses were melt-quenched at different nickel oxide concentrations. XRD and DSC techniques were characterized whether the samples are glass or crystalline materials. IR, Raman, and optical absorption techniques are used to obtain structural details. The IR spectra have revealed that the glass network contained conventional structural units GeO4 and GeO6. The Ni2+ ion octahedral transition exhibited luminescence spectra in the region of 1200–1500 nm; it is due to 3T2 (3F) → 3A2(3F) transition. The glasses containing the highest concentration of NiO have been found to have high values of luminescence efficiency and the cross-section. The dielectric characteristics, such as the dielectric constant, loss, and a.c. conductivity (σac), were analyzed across extensive frequency and temperature ranges, with a specific emphasis on the nickel oxide concentration. Analyzing optical absorption and dielectric properties of the samples, it has been found that nickel ions’ majority occur in tetrahedral sites. It is proved that the dielectric constant and loss values are highest for the sample N10 and ac conductivity due to dipoles being lowest for the sample N10. It is revealed that the glasses are highly conducting due to the modifying action of Ni2+ ions so these glasses are suitable for solid electrolyte uses besides their optical applications in NLO devices.