Photocatalytic Reduction of Cr(VI) to Cr(III) and Photocatalytic Degradation of Methylene Blue and Antifungal Activity of Ag/TiO2 Composites Synthesized via the Template Induced Route

Author:

Zahid Zunaira1,Rauf Abdul1ORCID,Javed Mohsin1ORCID,Alhujaily Ahmad2,Iqbal Shahid3ORCID,Amjad Adnan1,Arif Muhammad1,Hussain Sajjad4,Bahadur Ali5ORCID,Awwad Nasser S.6ORCID,Ibrahium Hala A.78,Al-Fawzan Foziah F.9,Elkaeed Eslam B.10ORCID

Affiliation:

1. Department of Chemistry, University of Management and Technology, Lahore 54770, Pakistan

2. Biology Department, College of Science, Taibah University, Al Madinah Al Munawarah 41477, Saudi Arabia

3. Department of Chemistry, School of Natural Sciences (SNS), National University of Science and Technology (NUST), H-12, Islamabad 46000, Pakistan

4. School of Chemistry, Faculty of Basic Sciences and Mathematics, Minhaj University, Lahore 54000, Pakistan

5. Department of Chemistry, College of Science and Technology, Wenzhou-Kean University, Wenzhou 325060, China

6. Chemistry Department, Faculty of Science, King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia

7. Biology Department, Faculty of Science, King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia

8. Department of Semi Pilot Plant, Nuclear Materials Authority, P.O. Box 530, El-Maadi, Cairo 11381, Egypt

9. Department of Chemistry, College of Science, Princess Nourah bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi Arabia

10. Department of Pharmaceutical Sciences, College of Pharmacy, AlMaarefa University, Riyadh 13713, Saudi Arabia

Abstract

Water treatment through photocatalysts has become an important topic regarding environmental protection. In the present study, silver and TiO2 (Ag/TiO2) composites for photocatalysts were effectively synthesized by adopting the template induced method. The prepared samples were characterized using XRD, FTIR spectroscopy, SEM, and EDX. The constructed samples’ particle size and shape were evaluated using a SEM, and the XRD patterns showed anatase crystalline phases. Their morphologies were controllable with changing concentration of reactants and calcination temperature. The synthesized composites act as catalyst in the degradation of methylene blue (MB) and reduction of Cr(VI) to Cr(III) under solar irradiation. In both of these activities, the best result has been shown by the 0.01 Ag/TiO2 composite. Methanol is used as the hole scavenger in the reduction of Cr(VI) to Cr(III). While the pH factor is important in the photocatalytic reduction of Cr(VI) to Cr(III). According to observations, S. macrospora and S. maydis were each subject to 0.01 Ag/TiO2 nanocomposites maximum antifungal activity, which was 38.4 mm and 34.3 mm, respectively. The outcomes demonstrate that both photocatalytic and antifungal properties are effectively displayed by the constructed material.

Publisher

MDPI AG

Subject

Inorganic Chemistry

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