Anisometric Ln(III) Complexes with Efficient Near-IR Luminescence

Abstract

Recent studies in development of near-infrared luminophores focus on overcoming their disadvantages such as low quantum efficiency, limited emission power, and broad emission spectra. Rare earth (RE) elements are promising compounds in this respect as they offer a unique set of optical properties that provide narrow emission spectra and large Stokes shifts. This work reports the results of synthesis and characterization of new anisometric complexes of lanthanide(III) tris(b-diketonates) and 1,10-phenanthroline. These complexes possess light emitting-properties in the near-infrared range. Due to their structural features, these complexes allow production of homogeneous films by spin coating. These films are transparent in the visible and near-infrared ranges (transmission up to 99%). This paper demonstrates advantages of Yb(III), Er(III), and Nd(III) complexes as potential components of highly efficient light-transforming NIR coatings.