MOFs for Electrochemical Energy Conversion and Storage

Abstract

Metal organic frameworks (MOFs) are a family of crystalline porous materials which attracts much attention for their possible application in energy electrochemical conversion and storage devices due to their ordered structures characterized by large surface areas and the presence in selected cases of a redox-active porous skeleton. Their synthetic versatility and relevant host-guest chemistry make them suitable platform for use in stable and flexible conductive materials. In this review we summarize the most recent results obtained in this field, by analyzing the use of MOFs in fuel and solar cells with special emphasis on PEMFCs and PSCs, their application in supercapacitors and the employment in batteries by differentiating Li-, Na- and other metal ion-batteries. Finally, an overview of the water splitting reaction MOF-catalyzed is also reported.