Composition and Textural Characteristics of Char Powders Produced by Thermomechanical Processing of Sunflower Seed Husks

Author:

Frolov Sergey M.1ORCID,Silantiev Anton S.1,Sadykov Ilias A.1,Smetanyuk Viktor A.1ORCID,Frolov Fedor S.1,Hasiak Yaroslav K.1,Dudareva Tatiana V.1,Bekeshev Valentin G.1ORCID,Grishin Maksim V.1,Golubev Evgeniy K.12ORCID,Baimukhambetova Dinara1,Popkova Vera Ya.1,Vezentsev Alexander I.3,Razdobarin Alexander E.3,Yapryntsev Maxim N.3ORCID,Sokolovskiy Pavel V.24ORCID

Affiliation:

1. Federal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, Russia

2. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 117393 Moscow, Russia

3. Department of General Chemistry, National Research University “Belgorod State University” (BSU), 308015 Belgorod, Russia

4. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia

Abstract

The paper presents the results of experimental studies on the production of fine char powder from sunflower seed husks by a novel method of thermomechanical treatment with pulsed shock waves and supersonic jets of the mixture of ultra-superheated (above 2000 °C) steam and carbon dioxide, as well as the results of examination of the produced char powder in terms of its chemical, phase, and granulometric composition and structural, morphological, and texture characteristics. The objective of the research is to explore the possibility of using the resulting char powder as a sorption-active material for organic substances. It is shown that the obtained char particles and their agglomerates have an average size of 20–30 nm and 12–24 µm, respectively, have the shape of disks and ellipsoids, consist mainly of amorphous carbon (up to 56 wt%) and oxygen (up to 42 wt%), and have a specific surface area of 1.1–1.7 m2/g. It is concluded that such a char powder can be used as an absorbent for organic substances when dried and deagglomerated.

Funder

Development of a technology for processing organic agricultural waste into adsorbents and backfill soils for landfills

Publisher

MDPI AG

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