Author:
Sun Manluan,Ge Sai,Zhao Jianguo,McDonald Robert,Ferguson Michael,Ma Guibin
Abstract
Three oxygen donor gallium(III) halide complexes, [GaX3(O=P(TMP)3] (TMP = trimethoxylphenyl and X = Cl− (1), Br− (2) and I− (3)), are prepared by oxidation in mixed solvents from their phosphine adducts of [GaX3(P(TMP)3]. Three crystalline compounds are obtained from the solutions and their crystal structures are determined in the solid state. It is rare to generate a crystalline phase for metal–adduct compounds of this bulky ligand; in this paper, three new crystal structures are presented.
Funder
National Natural Science Foundation of China
Shanxi Science and Technology Major Project
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering
Cited by
1 articles.
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