Ni-CeO2/SBA-15 Catalyst Prepared by Glycine-Assisted Impregnation Method for Low-Temperature Dry Reforming of Methane

Abstract

Developing low-temperature nickel-based catalysts with good resistance to coking and sintering for dry reforming of methane (DRM) is of great significance. In this work, Ni (5 wt%) and CeO2 (5 wt%) were supported on SBA-15 porous material by glycine-assisted impregnation method to obtain Ni-CeO2/SBA-15-G catalyst. XRD and TEM results showed that the addition of glycine can effectively promote the dispersion of NiO and CeO2 in the pores of SBA-15. H2-TPR and XPS results confirmed the formation of stronger metal-support interaction. In addition, after the addition of glycine, the NixCe1−xOy solid solution content was increased significantly, meanwhile, the Ce3+ concentration was increased from 31% to 49%, accompanied by more oxygen vacancies and generation of active oxygen species. For the above reasons, Ni-CeO2/SBA-15-G had better catalytic performance in the low-temperature DRM test (20 h, 600 °C) with high GHSV (600,000 mL/gcat/h), its CH4 conversion after reaction of 20 h was 2 times that of Ni-CeO2/SBA-15-C catalyst prepared by a conventional impregnation method. TGA-DTA test also proved that Ni-CeO2/SBA-15-G almost completely eliminated carbon deposition. The above advantages of the Ni-CeO2/SBA-15-G catalyst may have originated from the complexation of glycine with metal cations and can prevent them from gathering.