Abstract
Owing to the increasing generation of waste coffee powder and the biochar from this waste being considered as alternative conductive carbon fillers, we developed eco-friendly and electrically conductive cementitious composites using biochar from waste coffee beans, which were directly pyrolyzed into eco-friendly and electrically conductive biochar. Via carbonization and graphitization, cyclic organic carbon precursors were transformed into sp2-bonded carbon structures and then functionalized with melamine. The non-covalent functionalization process driven by the electromagnetic process accelerated the mass production and enhanced the monodispersive properties of the cementitious composites. Thus, the melamine-functionalized biochar cementitious composites exhibited an electrical conductivity of 3.64 × 10−5 ± 1.02 × 10−6 S/cm (n = 6), which corresponded to an improvement of over seven orders of that of pure concrete. Furthermore, the percolation threshold of biochar was between 0.02 and 0.05 wt.%; thus, an effective conductive network could be formed using low additions of functionalized biochar. As a result, in this study, electrically conductive cementitious composites were developed using waste coffee powder converted into carbon nanomaterials through a newly introduced process of non-covalent functionalization with melamine.
Funder
Ministry of Land, Infrastructure and Transport
National Research Foundation of Korea
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering
Cited by
3 articles.
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