Director Fluctuations in Two-Dimensional Liquid Crystal Disclinations

Abstract

We present analytical calculations of the energies and eigenfunctions of all normal modes of excitation of charge +1 two-dimensional splay (bend) disclinations confined to an annular region with inner radius R1 and outer radius R2 and with perpendicular (tangential) boundary conditions on the region’s inner and outer perimeters. Defects such as these appear in islands in smectic-C films and can in principle be created in bolaamphiphilic nematic films. Under perpendicular boundary conditions on the two surfaces and when the ratio β=Ks/Kb of the splay to bend 2D Frank constants is less than one, the splay configuration is stable for all values μ=R2/R1. When β>1, the splay configuration is stable only for μ less than a critical value μc(β), becoming unstable to a “spiral” mixed splay-bend configuration for μ>μc. The same behavior occurs in trapped bend defects with tangential boundary conditions but with Ks and Kb interchanged. By calculating free energies, we verify that the transition from a splay or bend configuration to a mixed one is continuous. We discuss the differences between our calculations that yield expressions for experimentally observable excitation energies and other calculations that produce the same critical points and spiral configurations as ours but not the same excitation energies. We also calculate measurable correlation functions and associated decay times of angular fluctuations.