Constructing Supramolecular Frameworks Based Imidazolate-Edge-Bridged Metallacalix[3]arenes via Hierarchical Self-Assemblies

Abstract

Hierarchical self-assembly of novel supramolecular structures has obtained increasing attention. Herein we design and synthesize the palladium(II)-based molecular basket-like structures, as structural analog of metallacalix[3]arene [M3L3]3+ (M = (dmbpy)Pd, (phen)Pd; dmbpy = 4,4’-dimethyl-bipyridine; phen = 1,10-phenanthroline), by coordination-driven self-assembly from imidazolate-containing ligand [4,5-bis(2,5-dimethylthiophen-3-yl)-1H-imidazole (HL) with palladium(II) nitrate precursors (dmbpy)Pd(NO3)2 and (phen)Pd(NO3)2. The difference of the palladium(II) nitrate precursors with π-surface in complex produces variations of the two-dimensional (2-D) and three-dimensional (3-D) high-ordered supramolecular architectures, constructed by π···π packing and hydrogen bonding interactions, with metallacalixarenes as building blocks. These results provide perceptions of further exploring the hierarchical assembly of supramolecular structures based on π···π packing and multiple hydrogen bonding.