New Copper Bromide Organic-Inorganic Hybrid Molecular Compounds with Anionic Inorganic Core and Cationic Organic Ligands

Abstract

Here, organic-inorganic hybrid molecular compounds based on copper(I) bromide have been synthesized by slow-diffusion method. The inorganic modules of these two structures are Cu2Br42− anion, and the inorganic modules are coordinated to cationic organic ligands via Cu-N coordinative bonds. Both of these compounds are luminescent, emitting green emissions under UV excitation.