Abstract
In this work, we report the synthesis of the nido-carborane-substituted ruthenium complexes and the substituent effects of nido-carboranes on the optical properties. Initially, from the optical measurements, it is shown that deep-red phosphorescence was obtained from the synthesized molecule, and the phosphorescent quantum yields were significantly improved by loading onto a polyethylene glycol film. This result represents that nido-carborane can work as a strong electron donor and should be an effective unit for enhancing the solid-state phosphorescence of ruthenium complexes. Further, it is suggested that the electron-donating properties of the nido-carborane units and subsequently the optical properties can be tuned by controlling the conformation of the nido-carborane units with the steric substituents. We demonstrate in this study the potential of nido-carborane as a building block for constructing optical materials as well as fundamental information regarding electronic interactions with π-conjugated systems.
Funder
the Nakatani Foundation
Japan Society for the Promotion of Science
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering
Cited by
6 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献