Effect of Bi on the Performance of Al-Ga-In Sacrificial Anodes

Abstract

Cathodic protection is widely used for metal corrosion protection. To improve their performance, it is necessary and urgent to study the influence of metal oxides on the microstructure and performance of aluminum alloy sacrificial anodes. Taking an Al-Ga-In sacrificial anode as the research object, the dissolution morphology and current efficiency characteristics were studied by means of electrochemical testing and microstructural observation, and the influence of varying Pb and Bi contents on the performance of an aluminum alloy sacrificial anode was investigated. The test results reveal that: (1) The Al-Ga-In sacrificial anode with 4% Pb and 1% Bi contents exhibits the best sacrificial anode performance. (2) The inclusion of an appropriate Bi element content shifts the open-circuit potential in a negative direction and promotes activation dissolution. Conversely, excessive Bi content leads to uneven dissolution, resulting in the shedding of anode grains and greatly reducing the current efficiency. (3) During the activation dissolution of the aluminum alloy, the second phase preferentially dissolves, and the activation point destroys the oxide film, resulting in the dissolution of the exposed aluminum matrix. Consequently, the concentration of dissolved metal ions is reduced and deposited back on the surface of the anode sample, promoting the continuous dissolution of the anode.