Climbing Colloidal Suspension

Abstract

Mixtures of powder and liquid are ubiquitous in nature as well as industries and exhibit complex flowing and deforming behaviors, including sol to gel transition under shear stress. In order to better understand the characteristic features of this type of mixture, we observed the behavior of a mixture of colloidal silica particles and water as a model system under vibration. The mixture showed different states, from powder-like to viscous fluid-like, with increasing content of water. At certain concentrations of silica particles (around 70 wt. %) and under relatively faster vibration (over 17 Hz), we observed that the colloidal suspension of silica particles and water climbed up the wall of a container against gravity. The main purpose of this paper is to report how we can observe the climbing suspension of colloidal silica. The rheological measurements of the climbing suspension demonstrated that the climbing suspension showed shear-thickening behavior, where force chain networks and normal stress differences are considered to develop. Therefore, we speculate that the transient formation and breaking of force networks and normal stress differences under vibration contribute to the occurrence of the climbing suspension. The tunable nature of colloidal suspensions may help to elucidate the climbing mechanism in the future.