Modelling of Propylene Polymerization in a Loop Reactor on the Titanium–Magnesium Catalyst Taking into Account the Transformation of Active Centers

Abstract

The volume of consumed and produced polymers is increasing in the market every day. This is due to the indispensability and convenience of polymers in all industries. The article presents the distinctive features of the use of titanium–magnesium catalysts in the process of propylene polymerization. A mathematical model of the polypropylene polymerization is presented. This model is the basis of creating an expert control complex of the propylene–ethylene block copolymer (PEBC) synthesis process and allowing a quantitative connection to be made between technological parameters of reactors, which allows control of the technological mode with the acceptable accuracy. The experiment catalytic system is microspheric titanium trichloride (MS-TiCl3) and co-catalyst-diethylaluminum chloride. Dependences of different parameters on others are illustrated. The result of the research is as follows: according to the calculations, when increasing the number of blocks in the chain, the average values of molecular weights increase and the polydispersity index decreases; changing the values of the transformation rate coefficients of active centers by the donor k 12 and k 21 allows research into the effect of the donor type.