Supercritical CO2 Extraction of Natural Compounds from Capuchin (Tropaeolum majus) Leaves and Seeds

Author:

Corrêa Gabriel1,Souza Michel Rubens dos Reis2,Nascimento Eduardo Soares3,Rodrigues Bjerk Thiago2ORCID,Goncalves José Eduardo4ORCID,Moritz Cristiane Mengue Feniman5ORCID,Sakai Otávio Akira6ORCID,Silva Erivaldo Antônio da3,Santos Renivaldo José dos7ORCID,da Silva Edson Antônio8,Cardozo-Filho Lucio9,Zanette Andreia Fatima1,Ferreira-Pinto Leandro1ORCID

Affiliation:

1. Department of Engineering, School of Engineering and Sciences, São Paulo State University (UNESP), Rosana 19274-000, SP, Brazil

2. Institute of Technology and Research (ITP), Aracaju 49032-490, SE, Brazil

3. Department of Cartography, School of Science and Technology, São Paulo State University (UNESP), Presidente Prudente 19060-900, SP, Brazil

4. Programa de Pós-Graduação em Tecnologias Limpas, Universidade Cesumar e Instituto Cesumar de Ciência, Tecnologia e Inovação (ICETI), Maringá 87050-390, PR, Brazil

5. State University of Maringá, Umuarama Regional Campus, Umuarama 87506-370, PR, Brazil

6. Federal Institute of Paraná (IFPR), Umuarama 87507-014, PR, Brazil

7. Postgraduate Program in Science and Technology of Materials (POSMAT), School of Engineering and Sciences, São Paulo State University (UNESP), Rosana 19274-000, SP, Brazil

8. Centro de Engenharias e Ciências Exatas, Universidade Estadual do Oeste do Paraná, Toledo 85903-000, PR, Brazil

9. Programa de Pós-Graduação em Engenharia Química, Universidade Estadual de Maringá, Maringá 87020-900, PR, Brazil

Abstract

This study investigated the supercritical CO2 extraction of oils from capuchin (Tropaeolum majus) seeds (4.34% moisture content) and leaves (5.26% moisture content) and analyzed the effects of varying temperature and pressure conditions. The extraction yields were 3% for the seeds and 2% for the leaves. The seed extracts were rich in oleic, linoleic, and palmitic fatty acids, whereas the leaf extracts contained a high concentration of octacosanol (73.37%). Kinetic analysis revealed distinct mass transfer mechanisms during extraction, and the Sovová model effectively described the extraction kinetics, showing good agreement with experimental data (ADD% < 4%). An analysis of variance (ANOVA) demonstrated the impact of temperature and pressure on the yields, with temperature being the most influential factor. The experimental conditions ranged from 22 to 28 MPa and from 313.15 to 333.15 K. This study contributes to the understanding of capuchin oil extraction and its potential applications in various fields, owing to the presence of bioactive compounds.

Funder

Fundação de Amparo à Pesquisa do Estado de São Paulo

Publisher

MDPI AG

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