[2.2]Paracyclophane Derivatives as Building Blocks for Coordination Polymers-Reference-Cited by-同舟云学术

[2.2]Paracyclophane Derivatives as Building Blocks for Coordination Polymers

Published:2023-05-29 Issue:11 Volume:16 Page:4051
ISSN:1996-1944
Container-title:Materials
language:en
Short-container-title:Materials

Author:

Birsa Mihail Lucian¹^ORCID,Hopf Henning¹²,Jones Peter G.¹³,Sarbu Laura Gabriela¹^ORCID,Bahrin Lucian Gabriel¹⁴^ORCID

Affiliation:

1. Department of Chemistry, Alexandru Ioan Cuza University of Iasi, No. 11 Carol I Blvd., 700506 Iasi, Romania

2. Institute of Organic Chemistry, Technical University of Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany

3. Institute of Inorganic and Analytical Chemistry, Technical University of Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany

4. Center of Advanced Research in Bionanoconjugates and Biopolymers—Intelcenter, Petru Poni Institute of Macromolecular Chemistry, No. 41A Grigore Ghica Voda Alley, 700487 Iasi, Romania

Abstract

Several new di- and tetracarboxylic [2.2]paracyclophane derivatives were obtained via Suzuki coupling between the appropriately brominated [2.2]paracyclophanes and 4-(methoxycarbonyl)phenylboronic acid. The reaction of one of these products, namely pp-bis(4-carboxyphenyl)[2.2]paracylophane (12), with zinc nitrate afforded a 2D coordination polymer comprising zinc-carboxylate paddlewheel clusters linked together by cyclophane cores. The zinc center is five-coordinated in a square-pyramidal geometry, with a DMF oxygen atom at the apex and four carboxylate oxygen atoms in the base.

Publisher

MDPI AG

Subject

General Materials Science

Link

https://www.mdpi.com/1996-1944/16/11/4051/pdf

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