Abstract
The search for matrices and technological solutions for the reliable immobilization of volatile radionuclides and high-level waste (HLW) components is an actual radiochemical problem. Methods of obtaining of sodium alumino-iron phosphate (NAFP) and iron phosphate (FP) glass composite materials synthesized at temperatures of 450–750 °C, their structure and hydrolytic stability were investigated in this paper. The structure of the samples was studied by XRD and SEM-EDS. It was shown that, in the case of FP materials, the phase composition varies depending on the synthesis temperature, while NAFP materials have a complex multiphase composition at all crystallization temperatures. It has been established that the samples of the obtained glass composite materials have a high hydrolytic stability. At the same time, FP material obtained at 650 °C are the most stable, which makes this medium-temperature method of synthesis promising for the immobilization of volatile HLW components.
Funder
Russian Science Foundation
Subject
Energy (miscellaneous),Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electrical and Electronic Engineering,Control and Optimization,Engineering (miscellaneous),Building and Construction
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