Spatial Distribution and Evaluation of Arsenic and Zinc Content in the Soil of a Karst Landscape

Abstract

Karst features such as polje are highly vulnerable to natural and anthropogenic pollution. The main objectives of this study were to investigate the soil quality in the Ioannina polje (north-west Greece) concerning arsenic (As) and zinc (Zn), and delineate their origin as well as compare the As and Zn content in soil with criteria recorded in the literature. For this purpose, the geomorphological settings, the land use, and the soil physicochemical properties were mapped and evaluated, including soil texture and concentrations of aqua-regia extractable As and Zn. The concentration of elements was spatially correlated with the land use and the geology of the study area, while screening values were applied to assess land suitability. The results reveal that 72% of the total study area has a very gentle slope. This relief favors urban and agricultural activity. Thus, the urban and agricultural land used cover 92% of the total area. The spatial distribution for As and Zn in the soil of the study area is located on very gentle slopes and is strongly correlated with the geological parent materials and human-induced contamination sources. Arsenic and Zn can be considered enriched in the soil of the area studied. The median topsoil contents (in mg kg−1) for As (agricultural soil 16.0; urban soil 17.8) and Zn (agricultural soil 92.0; urban soil 95.0) are higher compared to the corresponding median values of European topsoils. Land evaluation suitability concerning criteria given from the literature is discussed. The proposed work may be helpful in the project of land use planning and the protection of the natural environment.