Sensing Capacity in Dysprosium Metal–Organic Frameworks Based on 5-Aminoisophthalic Acid Ligand

Author:

Cepeda JavierORCID,Blasco-Pascual IsabelORCID,Rojas Sara,Choquesillo-Lazarte DuaneORCID,Guerrero-Arroyo Francisco J.ORCID,Morales Diego P.ORCID,García Jose Ángel,Rodríguez-Diéguez AntonioORCID,Salinas-Castillo AlfonsoORCID

Abstract

Two novel metal-organic frameworks (MOFs), based on dysprosium as the metal and the 5-aminoisophthalic acid (5aip) ligand, have been solvothermally synthesized, with the aim of studying and modulating their luminescence properties according to the variation of solvent in the structure. These materials display intense photo-luminescence properties in the solid state at room temperature. Interestingly, one fascinating sensory capacity of compound 2 regards obtaining a variation of the signal, depending on the solvent to which it is exposed. These results pave the way for a new generation of sensitive chemical sensors.

Funder

Ministry of Science, Innovation and Universities

Gobierno Vasco/Eusko Jaurlaritza

University of the Basque Country

Junta de Andalucía

Publisher

MDPI AG

Subject

Electrical and Electronic Engineering,Biochemistry,Instrumentation,Atomic and Molecular Physics, and Optics,Analytical Chemistry

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