Biogenic Orthorhombic α-Calcium Formate from Sediments of Alkali Lake, Oregon, USA-Reference-Cited by-同舟云学术

Biogenic Orthorhombic α-Calcium Formate from Sediments of Alkali Lake, Oregon, USA

Published:2021-04-23 Issue:5 Volume:11 Page:448
ISSN:2075-163X
Container-title:Minerals
language:en
Short-container-title:Minerals

Author:

Chukanov Nikita V.,Menor-Salvan Cesar^ORCID,Gurzhiy Vladislav V.^ORCID,Izatulina Alina R.^ORCID,Pekov Igor V.,Vigasina Marina F.^ORCID,Ksenofontov Dmitry A.,Britvin Sergey N.^ORCID

Abstract

Centimeter-sized crystals of orthorhombic calcium formate, α-Ca(HCO2)2 from Alkali Lake, Oregon, USA have been studied by means of powder and single-crystal X-ray diffraction analysis, infrared, and Raman spectroscopy. Based on the data on carbon isotope abundance in calcium formate and associated minerals, it was concluded that the formation of α-Ca(HCO2)2 may be a result of a combination of two factors: lake microbial metabolism and anthropogenic pollution with Agent Orange. Possible causes of stability of the low-density tetragonal β-Ca(HCO2)2 polymorph (formicaite) in boron ores are discussed.

Funder

President of Russian Federation grant to leading scientific schools

Publisher

MDPI AG

Subject

Geology,Geotechnical Engineering and Engineering Geology

Link

https://www.mdpi.com/2075-163X/11/5/448/pdf

Reference46 articles.

1. Formicaite, Ca(HCO2)2, a new mineral;Chukanov;Zap. Vseross. Miner. Obs. (Proc. Russ. Miner. Soc.),1999

2. Dashkovaite, Mg(HCO2)2·2H2O, a new formate mineral;Chukanov;Zap. Vseross. Miner. Ova. (Proc. Russ. Miner. Soc.),2000

3. Comparative study of the polymorphic species of strontium and calcium formates. I. Differential thermal analysis (DTA)

4. Comparative study of the polymorphic species of strontium and calcium formates. II. X-Ray diffraction

5. The structures of calcium formate β-Ca(HCOO)2 and δ-Ca(HCOO)2, and the tetragonal mixed crystals Ca(HCOO)2–Sr(HCOO)2

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