Oxidation Behavior and Kinetics Parameters of a Lean Coal at Low Temperature Based on Different Oxygen Concentrations

Abstract

The method of dividing the “three zones” of spontaneous combustion in goaf by oxygen volume fraction is the most widely used and effective method at present. However, the oxygen volume fraction method does not consider the influence of methane concentration in goaf, which is only applicable to low-gas goaf, not high-gassy goaf. In this work, the oxidation behavior and kinetics parameters of a lean coal at low temperatures under five different oxygen concentrations, including methane and its kinetics during low-temperature oxidation, were studied using temperature programming tests and thermogravimetric tests. The results showed that the decrease of oxygen content improves the adsorption capacity of coal to absorb different atmospheres at the initial stage. In the whole reaction process, there is a negative correlation between the strong-to-weak order of exothermicity and adsorption capacity, with a significant increase in apparent activation energy E. A marked hysteresis of the precipitation time of CO and CO2 and a decrease in their precipitation amount and a rise in the initial temperature for the generation of CO and CO2 were found.