Substantial Decrease in Contaminant Concentrations in the Sediments of the Venice (Italy) Canal Network in the Last Two Decades—Implications for Sediment Management

Abstract

The Venice canal network requires periodic intervention to remove sediments that progressively accumulate. The most recent dredging operation was carried out in the second half of the 1990s and early 2000s. These sediments had accumulated over a period of more than 30 years and were highly contaminated with Cd, Cu, Hg, Pb, Zn and PAHs. Sediments deposited after the dredging work were investigated in 2005, 2009, 2014 and 2017 by analysing sediment cores collected from three sites in the canal network. Arsenic, heavy metal and PAH concentrations were observed to be much lower than past values, although Cu, Hg and PAH levels were still relatively high. The high Cu concentrations (mean 161 mg kg−1) are partly due to the widespread use of Cu-based antifouling paint. Current Italian regulations forbid the disposal of dredged sediments with these concentrations inside the lagoon, thereby increasing the cost of canal network maintenance.