Evaluation of Groundwater and Grey Water Contamination with Heavy Metals and Their Adsorptive Remediation Using Renewable Carbon from a Mixed-Waste Source

Abstract

The contamination of water sources with heavy metals is a serious challenge that humanity is facing worldwide. The aim of this work was to evaluate and remediate the metal pollution in groundwater and greywater resources from Riyadh, Saudi Arabia. In addition, we investigated the application of ultrasonic power before adsorption to assess the dispersion of renewable carbon from mixed-waste sources (RC-MWS) as an adsorbent and enhance the water purification process. The renewable carbon adsorbent showed high ability to adsorb Pb(II), Zn(II), Cu(II), and Fe(II) from samples of the actual water under study. The conditions for the remediation of water polluted with heavy metals by adsorptive-separation were investigated, including the pH of the adsorption solution, the concentration of the heavy metal(s) under study, and the competition at the adsorption sites. The enhanced adsorption process exhibited the best performance at a pH of 6 and room temperature, and with a contact time of 60 min. Kinetic studies showed that the pseudo-second-order kinetic model was fitted with the adsorption of Pb(II), Zn(II), Cu(II), and Fe(II) onto the RC-MWS. The adsorption data were well fitted by Langmuir isotherms. The Freundlich isotherm was slightly fitted in the cases of Cu(II), Zn(II), and Fe(II), but not in the cases of Pb(II). The developed adsorption process was successfully applied to actual water samples, including water samples from Deria and Mozahemia and samples from clothes and car washing centers in Riyadh city.