Preparation of NiAl-AlMg6 Functionally Graded Composite Using the Energy of a Highly Exothermic Ti-C Mixture during Self-Propagating High-Temperature Synthesis

Author:

Denisov Igor1,Seropyan Stepan1ORCID,Malakhov Andrey1,Shakhray Denis2

Affiliation:

1. Merzhanov Institute of Structural Macrokinetics and Materials Science (ISMAN), Russian Academy of Sciences, 142432 Chernogolovka, Russia

2. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of Russian Academy of Sciences, 142432 Chernogolovka, Russia

Abstract

A functionally graded composite NiAl-AlMg6 was prepared using the pressure of gaseous reaction products (impurity gases) produced during the synthesis of reactive powders in a sealed reactor. It has been shown that this method can be used to prepare a NiAl/AlMg6 composite with both chaotically oriented pores in the NiAl layer and unidirectionally oriented pores (lotus-type pores). The pore shape in NiAl was found to be dependent on the pressure of the impurity gases and hydrogen present in the starting titanium powder. A mechanism for pore formation in NiAl and AlMg6 composite during SHS is proposed. Thus, functionally graded high-temperature composites can be produced by SHS in a sealed reactor using the chemical reaction energy and the pressure of impurity gases and hydrogen. Additionally, minimizing the influence of impurity gases on the contact zone increases the interface area between NiAl and AlMg6.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

MDPI AG

Subject

General Materials Science

Reference28 articles.

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