Detonability of Ammonium Nitrate Mixtures with the Addition of Organic Materials

Author:

Škrlec Vinko1ORCID,Sućeska Muhamed1ORCID,Dobrilović Mario1,Vincek Josip2

Affiliation:

1. Faculty of Mining, Geology and Petroleum Engineering, University of Zagreb, Pierottijeva 6, 10000 Zagreb, Croatia

2. Ministry of Physical Planning, Construction and State Assets, Ulica Republike Austrije 14, 10000 Zagreb, Croatia

Abstract

As an oxygen carrier and a strong oxidising agent, ammonium nitrate can create an explosive mixture when mixed with organic material. A typical example is the mixture of ammonium nitrate and fuel oil (ANFO), which is the most used explosive for civilian applications. In this work, we studied the detonability and detonation properties of mixtures of ammonium nitrate with recycled rubber and hay. The main goal of this study was to determine the optimal volume ratio of ammonium nitrate and organic materials in terms of achieving the best performance (working capacity). Using small experiments, it was determined that the maximum burst velocity for the ammonium nitrate/hay mixture is achieved at 8% hay by volume, while the maximum burst velocity for the ammonium nitrate/rubber mixture is achieved at 15% rubber by volume. A thermochemical calculation has shown that the maximum detonation heat is achieved at the zero oxygen balance at the volume ratios of 89.2/10.8 for AN/Rubber and 72.85/27.15 for AN/Hay.

Publisher

MDPI AG

Reference39 articles.

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3. Aziz, N. (2005). Proceedings of the 2005 Coal Operators’ Conference, University of Wollongong & the Australasian Institute of Mining and Metallurgy.

4. Nielsen, K., and Heltzen, A.M. (1987, January 23–26). Recent Norwegian Experiance with Polystyrene Diluted ANFO (ISANOL). Proceedings of the 2nd International Symposium on Rock Fragmentation by Blasting, Keystone, CO, USA.

5. Heltzen, A.M., and Kure, K. (, January February). Blasting with ANFO/Polystyrene Mixtures. Proceedings of the 6th Conference of Explosives and Blasting Techniques (ISEE), Clevland, OH, USA.

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