Hexakis(μ-3-aminopropanethiolato-1κ6N,S:2κ3S;3κ6N,S:2κ3S)cadmium(II)dirhodium(III) Dibromide Tetrahydrate-Reference-Cited by-同舟云学术

Hexakis(μ-3-aminopropanethiolato-1κ6N,S:2κ3S;3κ6N,S:2κ3S)cadmium(II)dirhodium(III) Dibromide Tetrahydrate

Published:2023-07-03 Issue:3 Volume:2023 Page:M1684
ISSN:1422-8599
Container-title:Molbank
language:en
Short-container-title:Molbank

Author:

Kouno Masahiro¹²^ORCID,Yoshinari Nobuto²^ORCID,Kojima Tatsuhiro²³^ORCID,Konno Takumi²⁴

Affiliation:

1. Hyogo Prefectural Institute of Technology, Kobe 654-0037, Japan

2. Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka 560-0043, Japan

3. Department of Applied Chemistry, Kobe City College of Technology, Kobe 651-2194, Japan

4. Department of Chemistry, College of Science, National Taiwan Normal University, Taipei 106, Taiwan

Abstract

Cadmium(II) complexes with thiolate ligands have received considerable attention because of their intriguing structural features and relevance to metalloproteins. In this study, a new cadmium(II)–rhodium(III) trinuclear complex, [Cd{Rh(apt)3}2]Br2·4H2O (1, apt = 3-aminopropanethiolate), was synthesized by the reaction of fac-[Rh(apt)3] with cadmium bromide. Compound 1 was characterized using elemental analysis, X-ray fluorescence and IR spectroscopies, and powder X-ray diffraction study. Single-crystal X-ray analysis revealed that the cadmium(II) center in 1 was surrounded by six thiolato S atoms from two fac-[Rh(apt)3] units.

Funder

JSPS KAKENHI

Proterial Materials Science Foundation

Publisher

MDPI AG

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://www.mdpi.com/1422-8599/2023/3/M1684/pdf

Reference29 articles.

1. Metallothioneins: Zinc, cadmium, mercury, and copper thiolates and selenolates mimicking protein active site features−structural aspects and biological implications;Henkel;Chem. Rev.,2004

2. Structural chemistry of complexes of (n − 1)d10 nsm metal ions with β-N-donor substituted thiolate ligands (m = 0, 2);Fleischer;Coord. Chem. Rev.,2005

3. Syntheses, stereochemistry, reactivity, and some properties of sulfur-bridged cobalt(III)–cadmium(II) polynuclear complexes derived from mononuclear cobalt(III) complex with D-penicillaminate;Yamada;Inorg. Chim. Acta,2002

4. Aggregation of Octahedral Thiolato Complexes by Forming Sulfur-Bridged Structures with Transition Metal Ions;Konno;Bull. Chem. Soc. Jpn.,2004

5. 3-Aminopropanethiol versus 2-Aminoethanethiol That Leads to Different S-Bridged Multinuclear Structures Composed of Rhodium(III) Octahedrons;Kouno;Chem. Lett.,2017