Nanoarchitectonics of Three-Dimensional Carbon Nanofiber-Supported Hollow Copper Sulfide Spheres for Asymmetric Supercapacitor Applications

Author:

Shin Miyeon1,Awasthi Ganesh Prasad2,Sharma Krishna Prasad2,Pandey Puran3ORCID,Park Mira4ORCID,Ojha Gunendra Prasad4ORCID,Yu Changho12ORCID

Affiliation:

1. Department of Energy Storage, Conversion Engineering of Graduate School, Jeonbuk National University, Jeonju 54896, Republic of Korea

2. Division of Convergence Technology Engineering, Jeonbuk National University, Jeonju 54896, Republic of Korea

3. Division of Physics and Semiconductor Science, Dongguk University, Seoul 04620, Republic of Korea

4. Carbon Composite Energy Nanomaterials Research Center, Woosuk University, Wanju 55338, Republic of Korea

Abstract

Three-dimensional carbon nanofiber (3D-CNF)-supported hollow copper sulfide (HCuS) spheres were synthesized by the facile hydrothermal method. The morphology of the as-synthesized HCuS@3D-CNF composite clearly revealed that the 3D-CNFs act as a basement for HCuS spheres. The electrochemical performance of as-synthesized HCuS@3D-CNFs was evaluated by cyclic voltammetry (CV) tests, gravimetric charge–discharge (GCD) tests, and Nyquist plots. The obtained results revealed that the HCuS@3D-CNFs exhibited greater areal capacitance (4.6 F/cm2) compared to bare HCuS (0.64 F/cm2) at a current density of 2 mA/cm2. Furthermore, HCuS@3D-CNFs retained excellent cyclic stability of 83.2% after 5000 cycles. The assembled asymmetric device (HCuS@3D-CNFs//BAC) exhibits an energy density of 0.15 mWh/cm2 with a working potential window of 1.5 V in KOH electrolyte. The obtained results demonstrate that HZnS@3D-CNF nanoarchitectonics is a potential electrode material for supercapacitor applications.

Funder

National Research Foundatiojn of Korea

Publisher

MDPI AG

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Computer Science Applications,Spectroscopy,Molecular Biology,General Medicine,Catalysis

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