The Effect of Fe Addition on the Curie Temperature and Magnetic Entropy of the Gd45Co50Al5 Amorphous Alloy

Author:

Li Luyi1ORCID,Tang Benzhen1,Fu Weijie1,Lu Ying1,Fu Yunqing1,Ding Ding2ORCID,Xia Lei2ORCID,Yu Peng1ORCID

Affiliation:

1. Chongqing Key Laboratory of Photo-Electric Functional Materials, College of Physics and Electronic Engineering, Chongqing Normal University, Chongqing 401331, China

2. Institute of Materials & Laboratory for Microstructure, Shanghai University, Shanghai 200072, China

Abstract

The new magnetic refrigeration (MR) technology, which uses the magnetocaloric effect (MCE) of materials for refrigeration, has shown apparent advantages over the compression refrigeration of freon and other gases. Therefore, how to obtain materials with excellent magnetic entropy change near room temperature is of great significance for the realization of MR. In order to achieve high Tc of a Gd-based amorphous alloy, Gd45Co50Al5 amorphous alloy with good room temperature MCE was selected, and a series of Gd45Co50−xFexAl5 (x = 2, 5, 10) amorphous alloys were prepared by adding Fe instead of Co. In this paper, the effect of Fe addition on the Curie temperature, and the magnetic entropy change in the alloys, were studied thoroughly. The results show that the Curie temperature is increased to 281 K by adding 5% Fe elements, which is mainly related to the enhanced 3d-3d interaction of transition elements caused by Fe addition, and the maximum value of magnetic entropy change is 3.24 J/(kg·K) under a field of 5 T. The results are expected to provide guidance for further improving the room temperature MCE of Gd-based amorphous alloys.

Funder

National Nature Science Foundation of China

Natural Science Foundation of Chongqing

Science and Technology Research Program of Chongqing Municipal Education Commission of China

Foundation of Chongqing Normal University

College Students Innovation and Entrepreneurship Training Program of Chongqing City

Publisher

MDPI AG

Subject

General Materials Science

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