Industrial Ceramics: From Waste to New Resources for Eco-Sustainable Building Materials

Author:

Fugazzotto Maura1ORCID,Mazzoleni Paolo1ORCID,Lancellotti Isabella2ORCID,Camerini Rachel3,Ferrari Pamela3,Tiné Maria4ORCID,Centauro Irene5ORCID,Salvatici Teresa5ORCID,Barone Germana1ORCID

Affiliation:

1. Department of Biological, Geological and Environmental Sciences, University of Catania, Corso Italia, 57, 95129 Catania, Italy

2. Department of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, Via Pietro Vivarelli, 10, 41125 Modena, Italy

3. Center for Colloid and Surface Science (CSGI) and Department of Chemistry, University of Florence, Via Della Lastruccia, 3, 50019 Sesto Fiorentino, Italy

4. Department of Chemistry and Industrial Chemistry, University of Pisa, Via Giuseppe Moruzzi, 13, 56124 Pisa, Italy

5. Department of Earth Science, University of Florence, Via La Pira, 4, 50121 Firenze, Italy

Abstract

Today, the need to dispose of a huge amount of ceramic industrial waste represents an important problem for production plants. Contextually, it is increasingly difficult to retrieve new mineral resources for the realization of building materials. Reusing ceramic industrial waste as precursors for building blocks/binders, exploiting their aluminosilicate composition for an alkaline activation process, could solve the problem. This chemical process facilitates the consolidation of new binders/blocks without thermal treatments and with less CO2 emissions if compared with traditional cements/ceramics. The alkali-activated materials (AAMs) are today thought as the materials of the future, eco-sustainable and technically advanced. In this study, six different kind of industrial ceramic waste are compared in their chemical and mineralogical composition, together with their thermal behaviour, reactivity in an alkaline environment and surface area characteristics, with the aim of converting them from waste into new resources. Preliminary tests of AAM synthesis by using 80%–100% of ceramic waste as a precursor show promising results. Workability, porosity and mechanical strengths in particular are measured, showing as, notwithstanding the presence of carbonate components, consolidated materials are obtained, with similar results. The main factors which affect the characteristics of the synthetized AAMs are the precursors’ granulometry, curing temperature and the proportions of the activating solutions.

Funder

Advanced Green Materials for Cultural Heritage (AGM for CuHe) project

Publisher

MDPI AG

Subject

Geology,Geotechnical Engineering and Engineering Geology

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