Abstract
After determining the optimum composition of the butyronitrile: ethylene carbonate: fluoroethylene carbonate (BN:EC:FEC) solvent/co-solvent/additive mixture, the resulting electrolyte formulation (1M LiPF6 in BN:EC (9:1) + 3% FEC) was evaluated in terms of ionic conductivity and the electrochemical stability window, as well as galvanostatic cycling performance in NMC/graphite cells. This cell chemistry results in remarkable fast charging, required, for instance, for automotive applications. In addition, a good long-term cycling behavior lasts for 1000 charge/discharge cycles and improved ionic conductivity compared to the benchmark counterpart was achieved. XPS sputter depth profiling analysis proved the beneficial behavior of the tuned BN-based electrolyte on the graphite surface, by confirming the formation of an effective solid electrolyte interphase (SEI).
Subject
Energy (miscellaneous),Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electrical and Electronic Engineering,Control and Optimization,Engineering (miscellaneous)
Cited by
19 articles.
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