Improved Tribological Properties of Epoxy Cement Reinforced with Impact-Resistant Core-Shell Structured Polymer Nanoparticles

Author:

Qiu Ling1,Wang Yuan2,Kong Xiaolan2,Li Yanan2,Cao Shiyu2,Hu Wenbin2,Zhang Gangqiang3ORCID,Wang Chenchen2

Affiliation:

1. Gansu Civil Engineering Research Institute Co., Ltd., Lanzhou 730000, China

2. School of Chemical and Environmental Engineering, Collaborative Innovation Center of Fragrance Flavour and Cosmetics, Shanghai Institute of Technology, Shanghai 201418, China

3. College of Textile and Clothing, Institute of Functional Textiles and Advanced Materials, State Key Laboratory of Bio-Fibers and Eco-Textiles, Collaborative Innovation Center of Marine Biomass Fibers Materials and Textiles of Shandong Province, Qingdao University, Qingdao 266071, China

Abstract

Traditional cement epoxy pavements suffer from inherent limitations such as terrible tribological properties, poor wear resistance, and weak impact resistance, presenting significant challenges to ensure the safety and continuous operation of urban roads. As a solution, high-performance cement epoxy composite grouting materials have emerged as the preferred option for engineering construction and road maintenance. In this study, CSP/epoxy cement (CSEC) composite materials were prepared by emulsion polymerization. The thermal properties of the materials were characterized, revealing that CSP enhances the thermal properties of epoxy cement (EC) to a certain extent. Furthermore, the frictional properties of CSEC composite materials and pure epoxy cement under different normal loads were investigated. The results indicated that the CSEC composite material exhibited a slight increase in friction coefficient and a notable decrease in wear rate compared to pure epoxy cement (EC). Specifically, the wear rate of CSEC decreased by 14.4% at a load of 20 N, highlighting the enhanced frictional performance facilitated by CSP. Mechanistic analysis attributed the improvement to the unique core-shell structure of CSP, which imparted higher impact resistance and eliminated alleviate residual stresses at the friction interface. This structural advantage further enhanced the wear resistance of materials, making it a promising choice for improving the durability and safety of urban road surfaces.

Funder

“ChenGuang” project

Shanghai Municipal Education Commission and Shanghai Education Development Foundation, and Shanghai “Science and Technology Innovation Action Plan” Morning Star Cultivation

Talent scientific research start-up project from Shanghai Institute of Technology

Collaborative Innovation Center of Fragrance Flavour and Cosmetics

Publisher

MDPI AG

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