Effects of Co-Solvents on the Performance of PEDOT:PSS Films and Hybrid Photovoltaic Devices

Abstract

Hybrid silicon solar cells have been fabricated by the spin coating of conductive polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as a p-type contact on textured n-type crystalline silicon wafers. The effect of adding co-solvents, ethylene glycol (EG) and dimethyl sulphoxide (DMSO), to PEDOT:PSS improves its conductivity which translates to the improved performance of solar cells. Transfer length measurements were conducted to realize optimal contact with minimal losses between the front metal contact (silver) and PEDOT:PSS. From the conductivity and device results, a 7% EG with 0.25 wt% Triton (surfactant) blend of PEDOT:PSS is found to be optimal for these cells. This current approach with a few changes in the device architecture will pave way for the further improvement of PEDOT:PSS based hybrid silicon solar cells.