Improvement of Laser-Induced Damage on High-Efficiency Solar Cells via Top-Hat Beam Ablation

Author:

Qian Feng1ORCID,Shen Honglie12,Huang Guoping3,Liu Biao1,Hong Juan4

Affiliation:

1. College of Materials Science and Technology, Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China

2. Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou University, Changzhou 213164, China

3. CECEP Solar Energy Technology (Zhenjiang) Co., Ltd., Zhenjiang 212132, China

4. College of Mechanical Engineering, Yancheng Institute of Technology, Yancheng 224051, China

Abstract

An important challenge in industrial laser ablation is laser-induced damage. In this study, reduced damage was achieved through the transition of the laser distribution from a Gaussian beam to a top-hat beam using diffractive optical elements (DOE), which overcome inhomogeneous irradiation. The higher peak fluence of a Gaussian beam far exceeded the ablation threshold and led to severely melted silicon at a higher depth covering the polished texture. The top-hat beam, with uniform irradiation, had a superior ablation characteristic and created a uniform square opening with the shallow melted silicon in the lift-off process. Thus, its effective minor carrier lifetime was 15.35% less at an ablated area fraction of 2% after re-passivation because of the decreased damage. After optimizing the ablation pattern with a top-hat beam, the local contacts improved the average open-circuit voltage (Voc) and short-circuit current (Isc) values of the cells due to the decreased damage and the uniform openings, but the damage induced by a Gaussian beam was too deep and can be partly restored under back surface field (BSF) formation. The overall increment in Isc and Voc enhanced the average efficiency by 0.05% of the absolute value for the PERC cells and 0.03% of the absolute value for bi-facial PERC cells.

Funder

National Natural Science Foundation of China

Publisher

MDPI AG

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