Migration Behavior and Influencing Factors of Petroleum Hydrocarbon Phenanthrene in Soil around Typical Oilfields of China

Abstract

Petroleum spills and land contamination are becoming increasingly common around the world. Polycyclic aromatic hydrocarbons (PAHs) and other pollutants found in petroleum are constantly migrating underground, making their migration in soil a hot research topic. Therefore, it is of great significance to evaluate the migratory process of petroleum hydrocarbons in petroleum-polluted soil to clarify its ecological and environmental risks. In this study, Phenanthrene (PHE) was used as a typical pollutant of PAHs. The soil was gathered from three typical oilfields in China, and a soil column apparatus was built to simulate the vertical migration of PHE in the soil. The migration law and penetration effect of PHE in various environmental conditions of soil were investigated by varying the ionic strength (IS), pH, particle size, and type of soil. According to the literature, pH has no discernible effect on the migration of PHE. The migration of PHE was adversely and positively linked with changes in IS and soil particle size, respectively. The influence of soil type was mainly manifested in the difference of organic matter and clay content. In the Yanchang Oilfield (YC) soil with the largest soil particle size and the least clay content, the mobility of PHE was the highest. This study may reveal the migration law of PAHs in soils around typical oilfields, establish a new foundation for PAH migration in the soil, and also provide new ideas for the management and control of petroleum pollution in the soil and groundwater.