Extraction of Cellulose Polymeric Material from Populus tremula Fibers: Characterization and Application to the Adsorption of Methylene Blue and Crystal Violet

Abstract

Cellulose is the most widely available biopolymer which is extensively used for several applications including textiles, composites, pharmaceutical, water treatment, etc. In this investigation, cellulose was chemically extracted from Populus tremula seed fibers. Samples were characterized using FT-IR, SEM, XRD, and TGA-DTA analyses. FT-IR spectrum of the extracted cellulose confirmed that hemicellulose and lignin were removed during alkali and bleaching treatments. SEM images showed the partially roughened surface of the fiber due to the removal of non-cellulosic elements and surface impurities during chemical modification. The crystallinity index values for untreated Populus tremula fibers and extracted cellulose were calculated to be 32.8% and 58.9%, respectively. The obvious increase in the crystallinity index for the extracted cellulose confirmed the removal of amorphous compounds present in raw populus. Alkali-treated populus fibers were more thermally stable than raw fibers. All changes observed after alkali and bleaching treatments evidenced the removal of amorphous contents and non-cellulosic components in raw populus fibers. Extracted cellulose exhibited excellent adsorption capacities of methylene blue (140.4 mg g−1) and crystal violet (154 mg g−1). The pseudo second order equation fitted well the kinetic data indicating a chemi-sorption process. The Freundlich model complied well with the experimental data suggesting that the adsorption of the studied dyes was multilayer.