Valorization of Date Palm Waste for Plastic Reinforcement: Macro and Micromechanics of Flexural Strength

Abstract

Date palm waste is an abundant agricultural residue in Tunisia and can be used for plastic reinforcement. Moreover, its use in plastic composites can help to reduce dependence on fossil resources for material production. In this work, the valorization of date palm residues was studied by employing high-yield processes following mechanical, chemical, and enzymatical treatments. Fibers obtained by soft chemical treatment with sodium hydroxide and enzymatic treatment with xylanases and pectinases were evaluated for their use in the reinforcement of plastic materials. The flexural strength property, truly relevant for structural, construction, automotive, or other market sectors, was adopted to assess the reinforcing potential of the fibers. Polypropylene was effectively reinforced with date palm fibers (60 wt.%), exhibiting a flexural strength increases of 80% (73.1 MPa), 93% (78.5 MPa), and 106% (83.9 MPa) for mechanical, chemical, and enzymatic fibers, respectively. The different treatments had an impact on the chemical composition of the fibers, and by extension on the final properties of the composites. The holocellulose content could provide good interfacial adhesion using a coupling agent, whereas the lignin content improved the dispersion of the phases. Two interesting outcomes were that the flexural performance of enzymatic fibers was like that of wood composites, whereas the specific flexural strength was comparable to that of glass fiber composites. Overall, the present work has shown the potential behind date palm waste in the composite sector when a specific property or application is desired. Novel treatments have been used for greater fiber compatibility, increasing the sustainability of the process, and improving the applicability of the palm residue.